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Empirical Formula worksheet

Grades 10–11

Solve each problem and show your work. Round answers to 2 decimal places where needed.

  1. Problem 1.
    • Amounts are: Masses in grams
    • Element 1: H (Hydrogen)
    • Amount of element 1: 42
    • Element 2: Eu (Europium)
    • Amount of element 2: 7.8
    • Element 3 (optional): Lv (Livermorium)
    • Amount of element 3: 40
    • Element 4 (optional): Mc (Moscovium)
    • Amount of element 4: 9
    • Molar mass of the compound (optional): 130 g/mol

    Find: Empirical formula

  2. Problem 2.
    • Amounts are: Masses in grams
    • Element 1: Br (Bromine)
    • Amount of element 1: 45
    • Element 2: Mn (Manganese)
    • Amount of element 2: 8
    • Element 3 (optional): Pt (Platinum)
    • Amount of element 3: 42
    • Element 4 (optional): Gd (Gadolinium)
    • Amount of element 4: 10
    • Molar mass of the compound (optional): 150 g/mol

    Find: Empirical formula

  3. Problem 3.
    • Amounts are: Mass percentages
    • Element 1: Ts (Tennessine)
    • Amount of element 1: 55
    • Element 2: At (Astatine)
    • Amount of element 2: 10
    • Element 3 (optional): Ag (Silver)
    • Amount of element 3: 50
    • Element 4 (optional): Br (Bromine)
    • Amount of element 4: 13
    • Molar mass of the compound (optional): 200 g/mol

    Find: Empirical formula

  4. Problem 4.
    • Amounts are: Mass percentages
    • Element 1: Pd (Palladium)
    • Amount of element 1: 43
    • Element 2: Si (Silicon)
    • Amount of element 2: 7.8
    • Element 3 (optional): Ag (Silver)
    • Amount of element 3: 54
    • Element 4 (optional): Sr (Strontium)
    • Amount of element 4: 10
    • Molar mass of the compound (optional): 120 g/mol

    Find: Empirical formula

  5. Problem 5.
    • Amounts are: Masses in grams
    • Element 1: Si (Silicon)
    • Amount of element 1: 50
    • Element 2: Nd (Neodymium)
    • Amount of element 2: 5.7
    • Element 3 (optional): Sm (Samarium)
    • Amount of element 3: 65
    • Element 4 (optional): Mn (Manganese)
    • Amount of element 4: 9
    • Molar mass of the compound (optional): 157.5 g/mol

    Find: Empirical formula

  6. Problem 6.
    • Amounts are: Mass percentages
    • Element 1: Tb (Terbium)
    • Amount of element 1: 55
    • Element 2: Se (Selenium)
    • Amount of element 2: 5.4
    • Element 3 (optional): Db (Dubnium)
    • Amount of element 3: 68
    • Element 4 (optional): Rb (Rubidium)
    • Amount of element 4: 6
    • Molar mass of the compound (optional): 140 g/mol

    Find: Empirical formula

  7. Problem 7.
    • Amounts are: Mass percentages
    • Element 1: Sg (Seaborgium)
    • Amount of element 1: 36
    • Element 2: Eu (Europium)
    • Amount of element 2: 5.5
    • Element 3 (optional): Sn (Tin)
    • Amount of element 3: 45
    • Element 4 (optional): Tl (Thallium)
    • Amount of element 4: 12
    • Molar mass of the compound (optional): 180 g/mol

    Find: Empirical formula

  8. Problem 8.
    • Amounts are: Masses in grams
    • Element 1: Os (Osmium)
    • Amount of element 1: 36
    • Element 2: P (Phosphorus)
    • Amount of element 2: 7.4
    • Element 3 (optional): O (Oxygen)
    • Amount of element 3: 44
    • Element 4 (optional): Cm (Curium)
    • Amount of element 4: 11
    • Molar mass of the compound (optional): 220 g/mol

    Find: Empirical formula

  9. Problem 9.
    • Amounts are: Masses in grams
    • Element 1: Si (Silicon)
    • Amount of element 1: 36
    • Element 2: Ag (Silver)
    • Amount of element 2: 8.4
    • Element 3 (optional): Hf (Hafnium)
    • Amount of element 3: 44
    • Element 4 (optional): Sm (Samarium)
    • Amount of element 4: 9
    • Molar mass of the compound (optional): 160 g/mol

    Find: Empirical formula

  10. Problem 10.
    • Amounts are: Masses in grams
    • Element 1: Ir (Iridium)
    • Amount of element 1: 45
    • Element 2: Hg (Mercury)
    • Amount of element 2: 6.6
    • Element 3 (optional): Fl (Flerovium)
    • Amount of element 3: 47
    • Element 4 (optional): He (Helium)
    • Amount of element 4: 11
    • Molar mass of the compound (optional): 170 g/mol

    Find: Empirical formula

Answer key: Empirical Formula worksheet

  1. 1. Empirical formula: H₄₀₂₈Eu₅Lv₁₃Mc₃

    1. Turn the grams of H into moles (a count of atoms): divide by its atomic weight, 1.008 g/mol

      42 g1.008 g/mol=41.666667 mol
    2. Turn the grams of Eu into moles (a count of atoms): divide by its atomic weight, 151.96 g/mol

      7.8 g151.96 g/mol=0.051329 mol
    3. Turn the grams of Lv into moles (a count of atoms): divide by its atomic weight, 293 g/mol

      40 g293 g/mol=0.136519 mol
    4. Turn the grams of Mc into moles (a count of atoms): divide by its atomic weight, 290 g/mol

      9 g290 g/mol=0.031034 mol
    5. Divide every mole amount by the smallest (0.031034 mol). That makes the scarcest element 1 and shows the ratio

      H 1,342.593 : Eu 1.654 : Lv 4.399 : Mc 1
    6. Some ratios aren't whole numbers, so multiply them all by 3. Atoms only come in whole numbers

      H 4,027.778 : Eu 4.962 : Lv 13.197 : Mc 3
    7. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      H 4028 : Eu 5 : Lv 13 : Mc 3 → H₄₀₂₈Eu₅Lv₁₃Mc₃
  2. 2. Empirical formula: Br₆₂Mn₁₆Pt₂₄Gd₇

    1. Turn the grams of Br into moles (a count of atoms): divide by its atomic weight, 79.904 g/mol

      45 g79.904 g/mol=0.563176 mol
    2. Turn the grams of Mn into moles (a count of atoms): divide by its atomic weight, 54.938 g/mol

      8 g54.938 g/mol=0.145619 mol
    3. Turn the grams of Pt into moles (a count of atoms): divide by its atomic weight, 195.08 g/mol

      42 g195.08 g/mol=0.215296 mol
    4. Turn the grams of Gd into moles (a count of atoms): divide by its atomic weight, 157.25 g/mol

      10 g157.25 g/mol=0.063593 mol
    5. Divide every mole amount by the smallest (0.063593 mol). That makes the scarcest element 1 and shows the ratio

      Br 8.856 : Mn 2.29 : Pt 3.386 : Gd 1
    6. Some ratios aren't whole numbers, so multiply them all by 7. Atoms only come in whole numbers

      Br 61.992 : Mn 16.029 : Pt 23.699 : Gd 7
    7. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Br 62 : Mn 16 : Pt 24 : Gd 7 → Br₆₂Mn₁₆Pt₂₄Gd₇
  3. 3. Empirical formula: Ts₁₂At₃Ag₂₉Br₁₀

    1. Take a 100 g sample, so each percentage becomes that many grams

      Ts: 55 g, At: 10 g, Ag: 50 g, Br: 13 g
    2. Turn the grams of Ts into moles (a count of atoms): divide by its atomic weight, 294 g/mol

      55 g294 g/mol=0.187075 mol
    3. Turn the grams of At into moles (a count of atoms): divide by its atomic weight, 210 g/mol

      10 g210 g/mol=0.047619 mol
    4. Turn the grams of Ag into moles (a count of atoms): divide by its atomic weight, 107.87 g/mol

      50 g107.87 g/mol=0.463521 mol
    5. Turn the grams of Br into moles (a count of atoms): divide by its atomic weight, 79.904 g/mol

      13 g79.904 g/mol=0.162695 mol
    6. Divide every mole amount by the smallest (0.047619 mol). That makes the scarcest element 1 and shows the ratio

      Ts 3.929 : At 1 : Ag 9.734 : Br 3.417
    7. Some ratios aren't whole numbers, so multiply them all by 3. Atoms only come in whole numbers

      Ts 11.786 : At 3 : Ag 29.202 : Br 10.25
    8. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Ts 12 : At 3 : Ag 29 : Br 10 → Ts₁₂At₃Ag₂₉Br₁₀
  4. 4. Empirical formula: Pd₇Si₅Ag₉Sr₂

    1. Take a 100 g sample, so each percentage becomes that many grams

      Pd: 43 g, Si: 7.8 g, Ag: 54 g, Sr: 10 g
    2. Turn the grams of Pd into moles (a count of atoms): divide by its atomic weight, 106.42 g/mol

      43 g106.42 g/mol=0.404059 mol
    3. Turn the grams of Si into moles (a count of atoms): divide by its atomic weight, 28.085 g/mol

      7.8 g28.085 g/mol=0.277728 mol
    4. Turn the grams of Ag into moles (a count of atoms): divide by its atomic weight, 107.87 g/mol

      54 g107.87 g/mol=0.500603 mol
    5. Turn the grams of Sr into moles (a count of atoms): divide by its atomic weight, 87.62 g/mol

      10 g87.62 g/mol=0.114129 mol
    6. Divide every mole amount by the smallest (0.114129 mol). That makes the scarcest element 1 and shows the ratio

      Pd 3.54 : Si 2.433 : Ag 4.386 : Sr 1
    7. Some ratios aren't whole numbers, so multiply them all by 2. Atoms only come in whole numbers

      Pd 7.081 : Si 4.867 : Ag 8.773 : Sr 2
    8. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Pd 7 : Si 5 : Ag 9 : Sr 2 → Pd₇Si₅Ag₉Sr₂
  5. 5. Empirical formula: Si₄₅NdSm₁₁Mn₄

    1. Turn the grams of Si into moles (a count of atoms): divide by its atomic weight, 28.085 g/mol

      50 g28.085 g/mol=1.78031 mol
    2. Turn the grams of Nd into moles (a count of atoms): divide by its atomic weight, 144.24 g/mol

      5.7 g144.24 g/mol=0.039517 mol
    3. Turn the grams of Sm into moles (a count of atoms): divide by its atomic weight, 150.36 g/mol

      65 g150.36 g/mol=0.432296 mol
    4. Turn the grams of Mn into moles (a count of atoms): divide by its atomic weight, 54.938 g/mol

      9 g54.938 g/mol=0.163821 mol
    5. Divide every mole amount by the smallest (0.039517 mol). That makes the scarcest element 1 and shows the ratio

      Si 45.051 : Nd 1 : Sm 10.939 : Mn 4.146
    6. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Si 45 : Nd 1 : Sm 11 : Mn 4 → Si₄₅NdSm₁₁Mn₄
  6. 6. Empirical formula: Tb₁₅Se₃Db₁₁Rb₃

    1. Take a 100 g sample, so each percentage becomes that many grams

      Tb: 55 g, Se: 5.4 g, Db: 68 g, Rb: 6 g
    2. Turn the grams of Tb into moles (a count of atoms): divide by its atomic weight, 158.93 g/mol

      55 g158.93 g/mol=0.346064 mol
    3. Turn the grams of Se into moles (a count of atoms): divide by its atomic weight, 78.971 g/mol

      5.4 g78.971 g/mol=0.06838 mol
    4. Turn the grams of Db into moles (a count of atoms): divide by its atomic weight, 268 g/mol

      68 g268 g/mol=0.253731 mol
    5. Turn the grams of Rb into moles (a count of atoms): divide by its atomic weight, 85.468 g/mol

      6 g85.468 g/mol=0.070202 mol
    6. Divide every mole amount by the smallest (0.06838 mol). That makes the scarcest element 1 and shows the ratio

      Tb 5.061 : Se 1 : Db 3.711 : Rb 1.027
    7. Some ratios aren't whole numbers, so multiply them all by 3. Atoms only come in whole numbers

      Tb 15.183 : Se 3 : Db 11.132 : Rb 3.08
    8. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Tb 15 : Se 3 : Db 11 : Rb 3 → Tb₁₅Se₃Db₁₁Rb₃
  7. 7. Empirical formula: Sg₂₂Eu₆Sn₆₃Tl₁₀

    1. Take a 100 g sample, so each percentage becomes that many grams

      Sg: 36 g, Eu: 5.5 g, Sn: 45 g, Tl: 12 g
    2. Turn the grams of Sg into moles (a count of atoms): divide by its atomic weight, 269 g/mol

      36 g269 g/mol=0.133829 mol
    3. Turn the grams of Eu into moles (a count of atoms): divide by its atomic weight, 151.96 g/mol

      5.5 g151.96 g/mol=0.036194 mol
    4. Turn the grams of Sn into moles (a count of atoms): divide by its atomic weight, 118.71 g/mol

      45 g118.71 g/mol=0.379075 mol
    5. Turn the grams of Tl into moles (a count of atoms): divide by its atomic weight, 204.38 g/mol

      12 g204.38 g/mol=0.058714 mol
    6. Divide every mole amount by the smallest (0.036194 mol). That makes the scarcest element 1 and shows the ratio

      Sg 3.698 : Eu 1 : Sn 10.473 : Tl 1.622
    7. Some ratios aren't whole numbers, so multiply them all by 6. Atoms only come in whole numbers

      Sg 22.185 : Eu 6 : Sn 62.841 : Tl 9.733
    8. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Sg 22 : Eu 6 : Sn 63 : Tl 10 → Sg₂₂Eu₆Sn₆₃Tl₁₀
  8. 8. Empirical formula: Os₃₄P₄₃O₄₉₄Cm₈

    1. Turn the grams of Os into moles (a count of atoms): divide by its atomic weight, 190.23 g/mol

      36 g190.23 g/mol=0.189245 mol
    2. Turn the grams of P into moles (a count of atoms): divide by its atomic weight, 30.974 g/mol

      7.4 g30.974 g/mol=0.23891 mol
    3. Turn the grams of O into moles (a count of atoms): divide by its atomic weight, 15.999 g/mol

      44 g15.999 g/mol=2.750172 mol
    4. Turn the grams of Cm into moles (a count of atoms): divide by its atomic weight, 247 g/mol

      11 g247 g/mol=0.044534 mol
    5. Divide every mole amount by the smallest (0.044534 mol). That makes the scarcest element 1 and shows the ratio

      Os 4.249 : P 5.365 : O 61.754 : Cm 1
    6. Some ratios aren't whole numbers, so multiply them all by 8. Atoms only come in whole numbers

      Os 33.995 : P 42.917 : O 494.031 : Cm 8
    7. Round to whole numbers to get the simplest formula

      Os 34 : P 43 : O 494 : Cm 8 → Os₃₄P₄₃O₄₉₄Cm₈
  9. 9. Empirical formula: Si₁₅₀Ag₉Hf₂₉Sm₇

    1. Turn the grams of Si into moles (a count of atoms): divide by its atomic weight, 28.085 g/mol

      36 g28.085 g/mol=1.281823 mol
    2. Turn the grams of Ag into moles (a count of atoms): divide by its atomic weight, 107.87 g/mol

      8.4 g107.87 g/mol=0.077872 mol
    3. Turn the grams of Hf into moles (a count of atoms): divide by its atomic weight, 178.49 g/mol

      44 g178.49 g/mol=0.246512 mol
    4. Turn the grams of Sm into moles (a count of atoms): divide by its atomic weight, 150.36 g/mol

      9 g150.36 g/mol=0.059856 mol
    5. Divide every mole amount by the smallest (0.059856 mol). That makes the scarcest element 1 and shows the ratio

      Si 21.415 : Ag 1.301 : Hf 4.118 : Sm 1
    6. Some ratios aren't whole numbers, so multiply them all by 7. Atoms only come in whole numbers

      Si 149.905 : Ag 9.107 : Hf 28.829 : Sm 7
    7. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Si 150 : Ag 9 : Hf 29 : Sm 7 → Si₁₅₀Ag₉Hf₂₉Sm₇
  10. 10. Empirical formula: Ir₁₄Hg₂Fl₁₀He₁₆₇

    1. Turn the grams of Ir into moles (a count of atoms): divide by its atomic weight, 192.22 g/mol

      45 g192.22 g/mol=0.234107 mol
    2. Turn the grams of Hg into moles (a count of atoms): divide by its atomic weight, 200.59 g/mol

      6.6 g200.59 g/mol=0.032903 mol
    3. Turn the grams of Fl into moles (a count of atoms): divide by its atomic weight, 290 g/mol

      47 g290 g/mol=0.162069 mol
    4. Turn the grams of He into moles (a count of atoms): divide by its atomic weight, 4.0026 g/mol

      11 g4.0026 g/mol=2.748214 mol
    5. Divide every mole amount by the smallest (0.032903 mol). That makes the scarcest element 1 and shows the ratio

      Ir 7.115 : Hg 1 : Fl 4.926 : He 83.525
    6. Some ratios aren't whole numbers, so multiply them all by 2. Atoms only come in whole numbers

      Ir 14.23 : Hg 2 : Fl 9.851 : He 167.05
    7. No small multiplier gives near-whole numbers, so this is the closest fit. Check the data

      Ir 14 : Hg 2 : Fl 10 : He 167 → Ir₁₄Hg₂Fl₁₀He₁₆₇